Question: op command does not work!!!

Dear Users!
Hope everyone is fine here. I have some questions about the following code:

Sol := {u[1, 1, 1, 1] = 0.2754389666e-1, u[1, 1, 1, 2] = 0.1305849194e-1, u[1, 1, 1, 3] = 0.2886163307e-2, u[1, 1, 1, 4] = -0.7346547512e-3, u[1, 1, 2, 1] = 0.4659732849e-1, u[1, 1, 2, 2] = 0.1466736306e-1, u[1, 1, 2, 3] = 0.2615590961e-3, u[1, 1, 2, 4] = -0.2999417306e-2, u[1, 2, 1, 1] = 0.4659732850e-1, u[1, 2, 1, 2] = 0.1466736306e-1, u[1, 2, 1, 3] = 0.2615590934e-3, u[1, 2, 1, 4] = -0.2999417305e-2, u[1, 2, 2, 1] = 0.7816751150e-1, u[1, 2, 2, 2] = 0.1319905841e-1, u[1, 2, 2, 3] = -0.3594991974e-2, u[1, 2, 2, 4] = -0.6810219469e-2, u[2, 1, 1, 1] = 0.4277449264e-1, u[2, 1, 1, 2] = -0.7962732407e-2, u[2, 1, 1, 3] = -0.1373208839e-1, u[2, 1, 1, 4] = -0.2756504221e-2, u[2, 1, 2, 1] = 0.7104313232e-1, u[2, 1, 2, 2] = -0.2934293200e-1, u[2, 1, 2, 3] = -0.1500623941e-1, u[2, 1, 2, 4] = -0.3113543133e-2, u[2, 2, 1, 1] = 0.7104313230e-1, u[2, 2, 1, 2] = -0.2934293199e-1, u[2, 2, 1, 3] = -0.1500623942e-1, u[2, 2, 1, 4] = -0.3113543128e-2, u[2, 2, 2, 1] = .1180017068, u[2, 2, 2, 2] = -0.7162229544e-1, u[2, 2, 2, 3] = -0.8898045960e-2, u[2, 2, 2, 4] = -0.9223166732e-2};
My aim is to write all the entries in Sol like the following way

u[1, 1, 1, 1] := 0.2754389666e-1;

u[1, 1, 1, 2] := 0.1305849194e-1;

u[1, 1, 1, 3] := 0.2886163307e-2;

and so on. For this I used the following logic (op command)

for i from 1 by 1 while i <= 32 do

lhs(op(i, Sol)) := rhs(op(i, Sol))

end do;
But it cant work. Please help me to solve my matter. I shall be greatful to you for your positive response. Please take care and thanks in advance.

Special request

@acer @Carl Love @Kitonum @Preben Alsholm